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Iron Skin was a Barbarian passive skill in early versions of Diablo III. It worked exactly as it did in the second game: toughened the Barbarian's skin, increasing armor by X%.
With the change of skill tree design, it was replaced with skills like Ignore Pain, Tough as Nails and Nerves of Steel.
With the introduction of Reaper of Souls, the skill of the same name has been added to the Crusader class.
Berserker Skills — Frenzy • Threatening Shout • Onslaught • Double Strike • Strong Constitution • Berserker State • Leap Attack • Enrage • Dual Wield Specialization • Savage • Speed Boost • Whirlwind • Slashing Strike • Relentless Attacks • Destroy Armor
Juggernaut Skills — Bash • Cleave • Ground Stomp • Focused Strength • Stubborn • Recovery • Taunt • Stunning Blows • Two-Handed Weapon Specialization • Invigorated • Seismic Slam • Revenge • Iron Will • Crushing Blows • Seismic Effect
Battlemaster Skills — Battle Rage • Perseverance • Power of the Battlemaster • Iron Skin • Hammer of the Ancients • Battle Cry • Scavenge • Critical Attacks • Shield Specialization • Furious Charge • Ignore Pain • Deliberate Defense • Improved Battle Rage • Death Proof • Inspiring Presence • Natural Resistance • Mighty Hammer